"The technology doesn't put people in jail, the justice system puts people in jail, and the only way evidence can be used to support a conviction is if that evidence supports that conviction."
If he evidence is from the technology and the technology is faulty then it can indeed result in wrongful convictions.
As someone directly involved in producing evidence one of the most stressful elements in my job was the possibility of being involved in a miscarriage of justice if I got it wrong. It rather seems as if distancing from the actual business of going into court has removed that concern for those developing this sort of technology.
In the Horizon instance the system was producing evidence of crimes were there was none. In more general situations, if there is a genuine crime and someone is wrongfully convicted it also means that the real perpetrator will have got away. That's something that should worry even the keenest advocate of raising conviction rates.