Charge on an electron is rounded
Ask Wolfram Alpha what is the charge on an electron and you will get an answer of 1.6021765x10^-19 C.
But the best avaiable data is the CODATA 2006, which is what is reffered to by both NIST in the USA and NPL in the UK.
http://physics.nist.gov/cuu/Constants/codata.pdf
Wolfram Alpha have the value from CODATA 2006, but it has been rounded to 8 significant digits. The internationally agreed value is 1.602176487x10-19 C, not the value Wolfram Alpha gives.
So far from being a 'primary source' as Wolfram Research claim, it is taking primary data and rounding it. Wikipedia has the right value.
I'm a user of Mathematica and find that program impressive, although the free open-source Sage looks as though it will be a thorne in the side of Wolfram Reserach. I was impressed the day I first see Mathematica - more than 20 years ago. But I can't see much of use in Wolfram Alpha. It appears to be a poor man's Mathematica. For most things web relatved, google is far more useful.
I'm sure Wolfram Alpha will improve over time, but I can't ever see it being too succesful myself.