No-compete restrictions are very limited in California but do operate at high levels in companies. No idea whether he was at that level or not. But Apple knows this law well and will have pegged it appropriately.
The more serious question is whether he took anything, *anything*, other than what was in his head. To do so is fatal in this environment. As is trying to recruit staff. No notebooks, no papers and certainly no electronic files of your designs. Your head is yours, and that's all.
You can do this "involuntary spinoff" thing in California but you have to be very, very careful.