Of Course
It's easy enough to keep time by microwaves, since they can be put into an electrical circuit that connects to a clock.
And it's easy enough to measure distances with the wavelength of light, just by using an interferometer.
That's why, in the past, while the second was defined as 9,192,631,770 oscillations of a hyperfine transition in Cesium-133, the metre had been defined as 1,650,763.73 wavelengths of the spectral line associated with the 2p10 to 5d5 transition of Krypton-86.
But then they decided to keep only the second, and define the speed of light as exactly 2.99792458 * 10^8 metres per second, requiring distance to be derived from microwaves, which are more suitable to measuring time than distance. I felt this was a mistake, but maybe I'm wrong, and they have found ways to manage to get an improvement in the accuracy of the metre out of this.
Now, we would have to switch to X-Rays. Which can't be seen in an interferometer, making it hard to measure distance with them, and whose oscillations we have no way to turn into electrical pulses for counting either. So we could have a supremely accurate definition of the metre and the second, but one that is impossible to actually put to use to calibrate anything.
Right now, the particular resonance involved is known to have an energy of 12.38959 keV. This is only seven digits, and we will need to know the value of the resonance to nineteen digits to even use it as a theoretical definition to the possible accurace of one part in 10^19.
So, while it is an interesting first step, who knows how long it's going to take to fill in the missing pieces?
Oh, wait a moment. It is possible to perform X-Ray diffraction experiments. So you diffract these X-Rays from scandium with a crystal, and once you measure the angle by which they've diffracted... you have now measured the spacing between atoms in the crystal by one part in 10^19, and you can use that to calibrate something because that might actually be measurable directly. And no doubt there are other ways that scientists can figure out.