DANE TLSA records, the RFC states, give (for example) a mail server a way to say "I support TLS", and publish how SMTP clients can authenticate servers.
You don't need DANE for that - MTAs already declare their TLS capabilities.
[vic@perridge ~]$ dig +short mx theregister.co.uk
1 aspmx.l.google.com.
5 alt1.aspmx.l.google.com.
5 alt2.aspmx.l.google.com.
10 aspmx2.googlemail.com.
10 aspmx3.googlemail.com.
10 aspmx4.googlemail.com.
10 aspmx5.googlemail.com.
[vic@perridge ~]$ telnet aspmx.l.google.com. 25
Trying 64.233.167.26...
Connected to aspmx.l.google.com..
Escape character is '^]'.
220 mx.google.com ESMTP fi7si37083059wic.91 - gsmtp
ehlo example.com
250-mx.google.com at your service, [217.169.14.82]
250-SIZE 35882577
250-8BITMIME
250-STARTTLS
250-ENHANCEDSTATUSCODES
250-PIPELINING
250-CHUNKING
250 SMTPUTF8
As you can see, ElReg's MX supports the STARTTLS command, and all that without touching DANE...
Vic.